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Preface
前言
Chapter 1 Ionic Liquids
1.1 Ionic liquids
1.2 Properties of ionic liquids
1.3 Synthesis of ionic liquids
1.4 Dissolution of metal catalysts in ionic liquids
1.5 Ionic liquids analysed in this book
1.6 Catalysis in ionic liquids
References
Chapter 2 X-ray Photoelectron Spectroscopy
2.1 X-ray photoelectron spectroscopy
2.2 XPS experiment
2.3 XPS of ionic liquids
References
Chapter 3 XPS of Pure Ionic Liquids and Ionic Liquid Mixtures
3.1 Introduction
3.2 Varying the cation
3.3 Varying the anion
3.4 Ionic liquid mixture
3.5 Conclusions
References
Chapter 4 XPS of Solute-solvent Interaction in Ionic Liquids
4.1 Introduction
4.2 Formation of a phosphineimidazolylidene palladium complex
4.3 Pd as a probe of solute-solvent interactions
4.4 Selection of anions: correlation of binding energy to established metrics
4.5 Can the solvent environment be tuned?
4.6 Can anion basicity impact on the reaction rate?
4.7 Conclusions
References
Chapter 5 XPS of Metal-ligand Interaction in Ionic Liquids
5.1 Introduction
5.2 Detection of the rhodium centre in solution
5.3 Formation of the mono-phosphine rhodium complex
5.4 Investigation of the chelated diphosphine rhodium complex
5.5 Correlation of reaction selectivity and binding energy
5.6 Conclusions
References
Appendix A XP Spectra
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