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Part Ⅰ Introduction to Polymers
Chapter 1 Introduction
1.1 Introduction
1.2 Definition-Ⅰ
1.2.1 Monomers
1.2.2 Dimers, Trimers, and Oligomers
1.2.3 Polymers
1.2.4 Linear Polymers
1.2.5 Branched Polymers
1.2.6 Crosslinked Polymers
1.3 Definition-II
1.3.1 Copolymers
1.3.2 Terpolymers
1.3.3 Graft Copolymers
1.3.4 Thermoplastics
1.3.5 Elastomers
1.3.6 Thermosetting Resin
1.3.7 Polymer Blends
Chapter 2 Polymer Chemistry
2.1 Rubber Polymerization
2.1.1 Solution Polymerization
2.1.2 Emulsion Polymerization
2.1.3 Cation Polymerization
2.1.4 Anionic Polymerization
2.1.5 Coordination Polymers
2.2 Polymer Characterization
2.2.1 Qualitative Analysis of Polymer
2.2.2 Quantitative Analysis of Polymer
2.2.3 Thermal Analysis
Chapter 3 Polymer Physics
3.1 Configurational States
3.2 Molecular Architecture
3.3 Chain Structure
3.4 Primary,Secondary,and Tertiary Structure
3.5 Representative States of Rubber Aggregation
3.5.1 The Glassy Amorphous State
3.5.2 The Rubber Elastic State
3.6 Polymer Structure-Property Relationships
Part Ⅱ Rubber Materials and Science
Chapter 4 Raw Rubber
4.1 Introduction
4.1.1 Definition of Rubber
4.1.2 Testing of Rubber
4.1.3 Classification of Rubber
4.2 Natural Rubber(NR)
4.2.1 Manufacture of NR
4.2.2 Grading of NR
4.2.3 Constitution of NR
4.2.4 Structure of NR
4.2.5 Properties of NR
4.2.6 Application of NR
4.2.7 Substituent of NR
4.3 Styrene-Butadiene Rubber(SBR)
4.3.1 Classification of SBR
4.3.2 Structure of SBR
4.3.3 Properties of SBR
4.4 Polybutadiene Rubber(BR)
4.4.1 Manufacture and Grading of BR
4.4.2 Structure of BR
4.4.3 Properties of BR
4.4.4 Application of BR
4.5 Nitrile Rubber(NBR)
4.5.1 Grading of NBR
4.5.2 Structure and Properties of NBR
4.5.3 Compounding of NBR
4.5.4 Application and Development of NBR
4.6 Chloroprene Rubber(CR)
4.6.1 Manufacture and Grading of CR
4.6.2 Chemical Structure of CR
4.6.3 Properties of CR
4.6.4 Compounding and Application of CR
4.7 Ethylene-Propylene Rubber(EPR)
4.7.1 Grading of EPR
4.7.2 Structure and Properties of EPR
4.7.3 Compounding of EPR
4.8 Butyl Rubber(IIR)
4.8.1 Grading of IIR
4.8.2 Properties and Application of IIR
4.9 Special-Purpose Elastomers
4.9.1 Fluroprene Rubber(FPM)
4.9.2 Silicone Rubber(Q)
4.9.3 Polyurethanes(PU)
4.9.4 Epichlorohydrin(CO)
4.10 Thermoplastic Elastomers(TPE)
Chapter 5 Curing System
5.1 Introduction
5.2 Characterization of The Vulcanization Process
5.2.1 Moving-Die Rheometer
5.2.2 Curing Process(Curing Curve)
5.2.3 Effects of Vulcanization on The Properties of Vulcanizate
5.3 Sulfur Curing System
5.3.1 Constitution of Sulfur Curing System
5.3.2 Sulfur Curing Mechanism
5.3.3 Different Sulfur Curing System
5.4 Non-Sulfur Curing System
5.4.1 Vulcanization by the Action of Organic Peroxides
5.4.2 Metallic Oxide Curing System
5.4.3 Resin Curing System
5.4.4 Reversible Crosslinking Technique
Chapter 6 Reinforcing and Filling System
6.1 Introduction
6.2 Carbon Black
6.2.1 Manufacture of Carbon Black
6.2.2 Classification of Carbon Black
6.2.3 Properties of Carbon Black
6.2.4 Mechanical Properties of Filled Rubbers
6.3 Silica
6.3.1 Classification of Silica
6.3.2 Nature of Silica Surface
6.3.3 Chemistry of Silane Coupling Agents
6.4 Other Fillers
6.4.1 China Clays
6.4.2 Calcium Carbonate
6.4.3 Barium Sulfate
6.5 New Type of Fillers
Chapter 7 Stabilizer Systems
7.1 Introduction
7.2 Oxidation of Rubber
7.2.1 Mechanism of Oxidation
7.2.2 Influencing Factors
7.3 Ozone Attack
7.4 Antidegradant
7.4.1 Antidegradant Types
7.4.2 Selection Criteria of Antidegradant
Chapter 8 Plasticizers and Other Processing Aids
8.1 Introduction
8.2 Mechanism of Plastification
8.2.1 Lubricity Theory
8.2.2 Gel Theory
8.2.3 Free-Volume Theory
8.3 Types of Plasticizers
8.3.1 Petroleum-Based Plasticizer
8.3.2 Pine Tar and Pine Products
8.3.3 Synthetic Resins
8.3.4 Esters
8.4 Other Processing Aids
8.4.1 Natural Fats and Salts
8.4.2 Peptizers
8.4.3 Coupling Agents
Part Ⅲ Rubber Processing and Engineering
Chapter 9 Mastication and Mixing
9.1 Introduction
9.2 Machinery
9.2.1 Open-Mills
9.2.2 Internal Mixers
9.3 Mastication
9.3.1 Mechanical Force
9.3.2 Operating Temperature
9.3.3 Oxygen
9.4 Mixing
9.4.1 Mill Mixing
9.4.2 Internal Mixing
9.5 Quality Control of Rubber Compounds
Chapter 10 Calendering
10.1 Calendering Machinery
10.2 Calendering Technology
10.2.1 Unsupported Sheeting
10.2.2 Coating of Fabric and Steel
Chapter 11 Extruding
11.1 Extruder
11.2 Extruding Technology
11.3 Recent Extruder Design
Chapter 12 Curing Process
12.1 Curing Medium
12.2 Curing Method
12.2.1 Compressing Molding
12.2.2 Transfer Molding
12.2.3 Injection Molding
12.2.4 Open Curing
Part Ⅳ Rubber Recycling
Chapter 13 Rubber Recycling
13.1 Introduction
13.2 Retreading of Tire
13.2.1 Pre Cure
13.2.2 Mold Cure
13.3 Ground Tire Rubber
13.3.1 The Specifications of GTR
13.3.2 Producing Process for GTR
13.4 Reclaimed Rubber
13.4.1 Reclaiming Technology
13.4.2 Common Processes Used for Reclaiming
13.5 Pyrolysis
13.5.1 Introduction
13.5.2 Typical Pyrolysis Process——Vacuum Pyrolysis Process
13.5.3 Pyrolysis Yields
13.5.4 Properties of Pyrolysis Products
13.5.5 Pyrolytic Products Applications
13.6 Incineration of Rubber(Tire-Derived Fuel)
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