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作       者:吴宇平

出  版  社:化学工业出版社

出版时间:2020-10-01

字       数:73.4万

所属分类: 科技 > 工业技术 > 重工业

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《Introduction to New Energy Materials and Devices》一书,全面系统地介绍太阳能、氢能、生物质能、核能、动力电池、储能和燃料电池等研究的基础知识和*展。以储能和换能为顺序,先系统介绍了目前电化学储能系统,如锂离子电池、其他新型电池和超级电容器的工作机理、发展历史和*展;着介绍了常见的换能系统如燃料电池、太阳能电池、太阳能制氢的研究现状和未来趋势;*后简单介绍了生物质能、核能和其他新能源的发展展望。本书深浅出,每一章均从基础知识讲起,内容涉及材料、物理、化学、电子、机械等多学科,知识体系涉及固体物理、电化学、材料科学与基础、半导体物理与器件、薄膜技术与材料等。着从基础讲到应用,探讨对应储能换能器件的组装、存在的问题和发展方向。该书既避免枯燥的机理介绍,又能使读者在对储能换能器件的深了解中加深对机理的了解。本书采用全英文编写,不仅适合于高等院校与新能源领域相关的本科生、研究生的双语教材或参考书,也适合于相关的科研与管理工作者门参考之一。<br/>【作者】<br/>吴宇平,南京工业大学能源科学与工程学院院长,教授,博导。国家自然科学基金“杰出青年基金”获得者(2015),第十三批中组部“国家千人计划” 创业人才项目选者(2016),江苏省“双创计划”人才(2017),连续三年(2015-2017)选全球高被引学者名单,选全球具影响力的科研菁英名单(2015)。主要研究方向为新型储能体系及其关键材料的研究和发。目前主持完成国家自然科学基金项目4项、科技部国际合作项目1项,参加完成国家科技部“973”项目1项。目前主持国家杰出青年基金1项、国家自然科学基金委-广东省联合重项目1项,并参与了国家重研发计划“基于材料基因组技术的全固态锂电池及其关键材料研发”项目。已在国际专业学术期刊如Chem. Soc. Rev., Angew. Chem. Int. Ed.、Prog. Mater. Sci.、Energy Environ. Sci.、Adv. Mater.、Adv. Energy Mater.、Nano Lett.发表学术论文300余篇,37篇被列ESI本领域高引用文章,被SCI核心期刊引用超过1万余次,H-指数58;授权发明专利35项;编写了有关能源储存系统与材料的中英文著作6部,全球销量超过5万册;多次受邀到国外访问和/或作邀请报告和演讲;多次参加美国、澳大利亚、韩国、南非等国家的博士论文和科研项目行评审;并兼任多个国际会议的国际顾问。<br/>
目录展开

内容提要

Preface

Chapter 1 Introduction

1.1 Brief introduction to world energy consumption

1.2 History of various new energy materials and devices

1.2.1 Batteries

1.2.2 Supercapacitors

1.2.3 Fuel cells

1.2.4 Solar cells

1.2.5 Biomass energy

1.2.6 Nuclear energy

1.3 Principles of various new energy materials and devices

1.3.1 Principles of metal-ion secondary batteries

1.3.2 Principles of other secondary batteries

1.3.3 Principles of fuel cells

1.3.4 Principles of supercapacitors

1.3.5 Principles of solar cells

1.3.6 Principles of solar-to-hydrogen

1.3.7 Principles of biomass energy

1.3.8 Principles of nuclear energy

1.4 Some requirements for various new energy materials and devices

1.4.1 Requirements for lithium secondary batteries

1.4.2 Requirements of other secondary batteries

1.4.3 Requirements of fuel cells

1.4.4 Requirements of supercapacitors

1.4.5 Requirements of solar cells

1.4.6 Requirements of solar-to-hydrogen conversion

1.4.7 Requirements of biomass energy

1.4.8 Requirements of nuclear energy

1.5 About this book

References

Chapter 2 Lithium secondary batteries

2.1 Positive electrode materials for LIBs

2.1.1 LiCoO2-based positive electrode materials

2.1.2 LiNiO2-based positive electrode materials

2.1.3 LiMn2O4-based positive electrode materials

2.1.4 LiFePO4-based positive electrode materials

2.1.5 LiNi1-x-yCoxMnyO2 (NCM) positive electrode materials

2.2 Negative electrode materials for LIBs

2.2.1 Graphite

2.2.2 Si-based materials

2.2.3 Titanium oxides

2.3 Electrolytes for LIBs

2.3.1 Liquid electrolytes

2.3.1.1 Solvents for liquid electrolytes

2.3.1.2 Additives for liquid electrolytes

2.3.2 Solid electrolytes

2.3.2.1 Inorganic solid-state electrolytes

2.3.2.2 Polymer electrolytes

2.4 Separators for LIBs

2.4.1 The functions and characteristics of the separator

2.4.2 Separator types

2.4.2.1 First generation lithium battery separators

2.4.2.2 Second generation lithium battery separators

2.4.2.3 Third generation lithium battery separators

2.4.3 Separator preparation methods

2.4.3.1 Dry process

2.4.3.2 Wet process

2.5 Aqueous rechargeable lithium batteries

2.5.1 First generation aqueous rechargeable lithium batteries

2.5.1.1 Positive electrode materials

2.5.1.2 Negative electrode materials

2.5.2 Second generation aqueous rechargeable lithium batteries

2.5.3 Third generation aqueous rechargeable lithium batteries

2.5.4 Side-reactions with H2O and O2 in an electrolyte

2.5.5 Water-in-salt aqueous rechargeable lithium batteries

2.6 Li-sulfur batteries

2.6.1 Principles of Li-sulfur batteries

2.6.2 Sulfur positive electrodes

2.6.3 Electrolytes for Li-sulfur batteries

2.7 Li-air batteries

2.7.1 Water-based lithium-air batteries

2.7.2 Organic lithium-air batteries

2.7.3 Water-organic two-liquid system lithium-air batteries

2.7.4 Solid-state lithium-air batteries

2.7.5 Ionic liquid system lithium-air batteries

References

Chapter 3 Other secondary batteries

3.1 Redox flow batteries

3.1.1 Polysulfide bromide battery (PSB)

3.1.2 ZNBR battery

3.1.3 Vanadium redox flow battery (VFB)

3.2 Na-S battery

3.2.1 Principle of operation

3.2.2 The configuration of the NAS battery

3.2.3 NAS battery features

3.2.4 Composition and crystalline structure of b-alumina

3.2.5 Challenges of NAS batteries

3.3 Other metal-air batteries

References

Chapter 4 Fuel cells

4.1 Introduction

4.1.1 Some history

4.1.2 Ordinary fuel cells

4.1.3 Advantages and disadvantages of fuel cells

4.1.4 Types of fuel cells

4.2 Fuel cell thermodynamics

4.2.1 How a basic fuel cell works

4.2.2 Fuel cell performance

4.2.3 Fuel cell internal energy

4.2.4 First law of thermodynamics

4.2.5 The second law of thermodynamics

4.2.6 What are thermodynamic potential and enthalpy

4.2.7 The calculation of reaction enthalpy

4.2.8 The Gibbs free energy

4.2.9 Factors influencing reversible voltage and calculation

4.2.10 Ideal fuel cell efficiency and actual fuel cell efficiency

4.3 Fuel cell reaction kinetics

4.3.1 Current basic physical quantity calculation

4.3.2 Calculation of reaction rate

4.3.3 Tiffier equation

4.3.4 Responsive charge transfer

4.3.5 Charge transfer can cause voltage loss

4.3.6 The physical significance of conductivity

4.4 Fuel cell systems

4.4.1 General description of fuel cell systems

4.4.2 Fuel cell stack

4.4.3 Fuel transfer processing subsystem

4.4.4 Power transmission subsystem

4.4.5 Fuel cell design levels: the unit cell, the stack, and the system

4.5 Fuel cell based power systems

4.5.1 Hybrid fuel cell power system

4.5.2 Standalone fuel cell power system

4.5.3 Grid connected fuel cell power systems

4.6 Applications of fuel cells

4.6.1 Fuel cell vehicles

4.6.2 Telecommunications

4.6.3 Underwater vehicles

4.6.4 Future targets

4.7 Conclusion

References

Chapter 5 Supercapacitors

5.1 Introduction

5.2 Charge storage mechanism of supercapacitors

5.2.1 Electrochemical double-layer capacitors

5.2.2 Pseudocapacitors

5.2.3 Hybrid capacitor devices

5.3 Electrolytes

5.3.1 Aqueous electrolytes

5.3.2 Organic electrolytes

5.3.3 Ionic-liquid-based electrolytes

5.3.4 Solid- and quasi-solid-state electrolytes

5.4 Electrode materials for EDLCs

5.4.1 Carbon materials with different-scaled pores

5.4.2 Activated carbons (ACs)

5.4.3 Carbon nanotubes (CNTs)

5.4.4 Graphene-based electrode materials

5.4.5 Other carbon structures

5.5 Electrode materials for pseudocapacitors

5.5.1 Noble metal oxides

5.5.2 Transition metal oxides and hydroxides

5.5.3 Conducting polymers (CPs)

5.6 Hybrid capacitors

5.6.1 Acidic HCs

5.6.2 Alkaline HCs

5.6.3 Lithium-ion capacitors

5.6.4 Sodium-ion capacitors

5.7 Supercapacitor performance

5.8 Applications of supercapacitors

References

Chapter 6 Solar cells

6.1 Introduction

6.1.1 History

6.1.2 Classification of solar cells

6.1.3 Some PV parameters

6.1.4 Principles of solar cells

6.2 Silicon-based solar cells

6.2.1 Introduction to Si-based solar cells

6.2.2 Electrode materials

6.2.3 Basic processing and key materials

6.3 GaAs solar cells

6.3.1 History of the GaAs solar cell

6.3.2 Comparison with silicon-based solar cells

6.3.3 Other properties of GaAs materials

6.3.4 Performance of GaAs solar cells

6.4 Dye-sensitized solar cells

6.4.1 History of dye-sensitized solar cells

6.4.2 Principle of operation of a DSSC

6.4.3 Assembly of dye-sensitized solar cells

6.4.4 Main components of DSSCs

6.5 Organic /Polymer solar cells

6.5.1 History of the polymer solar cell

6.5.2 Principles of polymer solar cells

6.5.3 Advantages of polymer solar cells

6.5.4 Structure of a polymer solar cell

6.5.5 Key materials for polymer solar cells

6.5.6 Development of polymer solar cells

6.6 Perovskite solar cells

6.6.1 Perovskite solar cell history

6.6.2 Principles of perovskite solar cells

6.6.3 Key materials for perovskite solar cells

6.7 Solar power in China

References

Chapter 7 Solar-to-Hydrogen

7.1 Hydrogen energy

7.2 Hydrogen production from solar radiation

7.3 Direct solar thermal hydrogen generation

7.4 Concentrated solar thermochemical hydrogen production

7.4.1 Thermodynamics of solar thermochemical processes

7.4.2 Thermochemical processes

7.5 Solar photochemical hydrogen production

7.6 Photocatalytic hydrogen production

7.6.1 Principles of photocatalytic hydrogen generation

7.6.2 Key photocatalytic hydrogen generation processes

7.6.3 Evaluating photocatalytic water splitting systems

7.6.4 UV photocatalysts for water splitting

7.6.5 Visible light photocatalysts for H2 production

7.6.6 Main challenges and opportunities

7.7 Photobiological hydrogen generation

7.7.1 Biological hydrogen production processes

7.7.2 Microbiology

7.7.3 Key enzymes

7.7.4 Genetic modification of microorganisms

7.7.5 Theoretical considerations

7.7.6 Energy analysis and purification of hydrogen

7.8 Solar-hydrogen energy systems

References

Chapter 8 Biomass energy

8.1 Introduction of biomass energy

8.1.1 Definition and features

8.1.2 Main resource categories

8.1.3 Conversion technologies

8.1.4 The risks and rewards of energy from biomass

8.2 Biofuel characteristics

8.3 Bioethanol

8.3.1 Biomass resources

8.3.2 Detailed process technology

8.4 Biodiesel

8.4.1 Synthesis technology

8.4.2 Global biodiesel status

8.5 Gaseous biomass energy production

8.5.1 Biogas

8.5.2 Biomass gasification

8.6 Biomass power generation (BPG)

8.6.1 BPG in China

8.6.2 BPG in other countries

8.7 Outlook

References

Chapter 9 Nuclear energy

9.1 Introduction

9.2 What is nuclear energy

9.3 The physical basis of a nuclear reactor

9.3.1 The nucleus and nuclear energy

9.3.2 Radioactivity

9.3.3 Types and patterns of decay

9.3.4 Nuclear reactions

9.4 Nuclear electric power generation

9.5 Nuclear reactor types and raw materials

9.5.1 Nuclear reactor classification

9.5.2 Pressurized water reactor

9.5.3 Boiling water reactor

9.5.4 Heavy water reactor

9.5.5 Graphite reactor

9.6 Power generation principles

9.6.1 Advantages

9.6.2 Disadvantages

9.7 Nuclear resources

9.7.1 Marine nuclear resources

9.7.2 The nuclear resources of the moon

9.8 Nuclear safety

9.9 Nuclear energy development in China

References

Chapter 10 Other energy

10.1 Introduction

10.2 Wind energy

10.2.1 Development of wind energy

10.2.2 Utilization of wind energy

10.2.3 Wind turbines

10.2.4 The global wind energy situation

10.3 Geothermal energy

10.3.1 History of geothermal energy

10.3.2 Types of geothermal energy

10.3.3 Resources

10.3.4 Application scenarios of geothermal energy

10.3.5 Challenges of geothermal energy

10.4 Marine energy

10.4.1 Characteristics of marine energy

10.4.2 Forms of marine energy

10.4.3 Use patterns for electricity generation

10.4.4 Installed capacity of ocean energy

10.4.5 Challenges of ocean energy

10.4.6 Prospect forecast of ocean energy

10.5 Conclusion

References

Index

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