碳材料由于其结构多样性,导致其性能多样化,因而应用领域广阔,碳材料研究已受到全球材料科学界、物理学界、化学界的广泛关注。本书系统介绍了碳材料的科学理论知识和工程应用实例。书中首先介绍碳材料的分类与发展史,及其多样性;并围绕工艺-微观结构-性能之间的关系,对碳材料的制备技术、结构和性能作了系统归纳与总结;介绍碳材料,特别是新型碳材料的发展及其在环保、能源、制造业、国防等领域应用。书中还包括碳纳米管、纳米纤维、富勒烯、石墨烯等碳材料研究的**进展。
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Preface
Acknowledgments
Index
CHAPTER 1 Introduction
1.1 Carbon materials
1.2 Short history of carbon materials
1.3 Classic carbons, new carbons, and nanocarbons
1.3.1 Classic carbons
1.3.2 New carbons
1.3.3 Nanocarbons
1.4 Construction and purposes of the present book
References
CHAPTER 2 Fundamental Science of Carbon Materials
2.1 Carbon families
2.1.1 Carbon-carbon bonds
2.1.2 Carbon families
2.1.3 Structural relation to neighboring atoms
2.2 Structure and texture of carbon materials
2.2.1 Structure
2.2.2 Structure development with heat treatment (carbonization and graphitization)
2.2.3 Nanotexture
2.2.4 Microtexture (agglomeration)
2.3 Carbonization (nanotexture development)
2.3.1 Formation processes of carbon materials
2.3.2 Gas phase carbonization
2.3.3 Solid phase carbonization
2.3.4 Liquid phase carbonization
2.4 Novel techniques for carbonization
2.4.1 Template method
2.4.2 Polymer blend method
2.4.3 Electrospinning
2.4.4 Pressure carbonization
2.4.5 High-yield carbonization
2.4.6 Low-temperature carbonization
2.5 Graphitization (structure development)
2.5.1 Structure parameters
2.5.2 Graphitization behavior
2.5.3 Relations among structure parameters
2.5.4 Graphitization process
2.5.5 Graphitizing and non-graphitizing carbons
2.5.6 Heterogeneous graphitization (multiphase graphitization)
2.6 Acceleration of graphitization
2.6.1 Catalytic graphitization
2.6.2 Stress graphitization
2.6.3 Graphitization of exfoliated carbon fibers
2.7 Pore development in carbon materials
2.7.1 Pores in carbon materials
2.7.2 Identification of pores
2.7.3 Pore development in carbon materials
2.8 Introduction of foreign species
2.8.1 Possibility to introduce foreign species into carbon materials
2.8.2 Intercalation
2.8.3 Substitution
2.8.4 Doping
2.8.5 Dispersion of fine metal particles
References
CHAPTER 3 Engineering and Applications of Carbon Materials
3.1 Polycrystalline graphite blocks
3.1.1 Production
3.1.2 Applications
3.1.3 Filler cokes and binder pitches
3.1.4 Properties
3.2 Highly oriented graphite
3.2.1 Highly oriented graphite
3.2.2 Natural graphite
3.2.3 Kish graphite
3.2.4 Highly oriented pyrolytic graphite (HOPG)
3.2.5 Graphite films derived from polyimide films
3.2.6 Flexible graphite sheets
3.3 Non-graphitizing and glass-like carbons
3.3.1 Structural characteristics
3.3.2 Properties
3.3.3 Glass-like carbons
3.4 Carbon fibers
3.4.1 Classification of fibrous carbons
3.4.2 Characteristics of carbon fibers
3.4.3 PAN-based carbon fibers
3.4.4 Pitch-based carbon fibers
3.4.5 Vapor-grown carbon fibers
3.4.6 Glass-like carbon fibers
3.4.7 Carbon microcoils
3.5 Nanocarbons
3.5.1 Carbon nanotubes and nanofibers
3.5.2 Fullerenes
3.5.3 Graphene and its derivatives
3.5.4 Graphyne and graphdiyne
3.5.5 Single-wall carbon nanohorns
3.5.6 Helical carbon films
3.6 Porous carbons
3.6.1 Activated carbons
3.6.2 Novel techniques to control pore structure
3.6.3 Carbon foams (macroporous carbons)
3.7 Carbon-based composites
3.7.1 Carbon-based composites
3.7.2 Carbon/carbon composites
3.7.3 Carbon/plastics composites
3.7.4 Carbon/ceramics composites
3.7.5 Carbon/metal composites
3.8 Intercalation compounds
3.8.1 Possible applications
3.8.2 High conductivity function
3.8.3 Electrochemical functions
3.8.4 Catalytic functions
3.8.5 Gas adsorption and storage
3.8.6 Other functions
3.9 Carbon materials for energy storage
3.9.1 Rechargeable batteries
3.9.2 Electrochemical capacitors
3.9.3 Storage of hydrogen gas
3.9.4 Storage of methane gas
3.10 Carbon materials for environment remediation
3.10.1 Carbon/anatase composites
3.10.2 Carbon materials for sorption of viscous fluids
3.10.3 Carbon fibers for environment remediation
References
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